Ligand‐free Pd/Cu‐catalyzed decarboxylative coupling of aryl iodides with α‐oxocarboxylates |
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| Authors: | Yongfeng Ji Xiaomin Yang Weixi Mao |
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| Institution: | Department of Chemistry, College of Science, Hebei North University, Zhangjiakou, China |
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| Abstract: | This paper describes a palladium/copper‐catalyzed decarboxylative coupling of aryl iodides with α‐oxocarboxylates. The cross‐coupling reaction gives high chemical yields of aryl ketones and has wide functional group tolerance, making the transformation an attractive alternative to the traditional cross‐coupling approaches for aryl ketones. Copyright © 2014 John Wiley & Sons, Ltd. |
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| Keywords: | Pd/Cu‐catalyzed α ‐oxocarboxylates decarboxylative coupling aryl iodide |
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