Recyclable 1,2‐bis[3,5‐bis(trifluoromethyl)phenyl]diselane‐catalyzed oxidation of cyclohexene with H2O2: a practical access to trans‐1,2‐cyclohexanediol |
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| Authors: | Lei Yu Jun Wang Tian Chen Yuguang Wang Qing Xu |
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| Institution: | 1. Key Laboratory of Environmental Materials and Engineering of Jiangsu Province, School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu, China;2. Zhejiang Key Laboratory of Carbon Materials, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang, China;3. College of Biological and Environmental Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang, China |
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| Abstract: | 1,2‐Bis3,5‐bis(trifluoromethyl)phenyl]diselane‐catalyzed oxidation of cyclohexene by hydrogen peroxide affords a quick, clean and practical access to the important compound trans‐1,2‐cyclohexanediol under mild conditions. The highly atom‐economic properties, clean procedures, high reaction concentration, short reaction time, mild conditions and eco‐friendly, recyclable and low loading catalysts facilitate this methodology for possible future practical industrial production. Copyright © 2014 John Wiley & Sons, Ltd. |
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| Keywords: | selenium catalysis trans‐1 2‐cyclohexanediol oxidation |
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