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Sn‐mediated one‐pot four‐component allylation of aldimines
Authors:Jian Li  Wenxian Lv  Danfeng Huang  Ke‐Hu Wang  Teng Niu  Yingpeng Su  Yulai Hu
Institution:College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu, People's Republic of China
Abstract:A convenient and facile method for the synthesis of homoallylic amines was disclosed. The one‐pot reaction of aldehydes, aromatic amines and allylic bromide with tin powder at room temperature could afford the homoallylic amines in good to excellent yield without any promoter or additive. The method is highly efficient and environmentally benign with low cost and concise manipulation. Copyright © 2014 John Wiley & Sons, Ltd.
Keywords:tin powder  one‐pot  allylation  homoallylic amines
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