Acetanilide palladacycle: an efficient catalyst for room‐temperature Suzuki–Miyaura cross‐coupling reaction |
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| Authors: | Anindita Dewan Zenith Buragohain Manoj Mondal Gayatri Sarmah Geetika Borah Utpal Bora |
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| Institution: | 1. Department of Chemistry, Dibrugarh University, Dibrugarh 786004, Assam, India;2. Department of Chemical Sciences, Tezpur University, Tezpur 784028, Assam, India |
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| Abstract: | The catalytic activity of three acetanilide palladacycles derived from easily accessible and commercially available acetanilide derivatives, viz. N‐phenylacetamide ( L1 ), N‐(4‐chlorophenyl)acetamide ( L2 ) and N‐(4‐methylphenyl)acetamide ( L3 ) has been examined in Pd‐catalyzed Suzuki–Miyaura reaction of arylboronic acid with aryl bromides at room temperature. The complex 1L3 exhibited efficient activity in the Suzuki–Miyaura reaction (up to 99% isolated yield) under mild reaction conditions. Copyright © 2014 John Wiley & Sons, Ltd. |
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| Keywords: | palladacycle acetanilide Suzuki– Miyaura isopropanol biaryl |
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