| 配合物[Cu（C8H6CIO3）2（H2O）2]的合成与晶体结构 |
| |
| 引用本文： | 周永红.配合物[Cu（C8H6CIO3）2（H2O）2]的合成与晶体结构[J].化学研究,2010,21(1):1-4. |
| |
| 作者姓名： | 周永红 |
| |
| 作者单位： | 淮北煤炭师范学院,化学与材料科学系,安徽,淮北,235000;安徽省含能材料重点实验室,安徽,淮北,235000 |
| |
| 基金项目： | The project was supported by the Natural Science Foundation of Anhui Provincial Education Commission （NO. KJ2008B65ZC） and Open Foundation of Anhui Provincial Key Laboratory of Energetic Materials （NO. KLEM2009004）. |
| |
| 摘 要： | 以硝酸铜和对氯苯氧乙酸为原料，合成了标题化合物Cu（C8H6ClO3）2（H2O）2]，并用元素分析仪、红外光谱仪、X射线单晶衍射仪表征了其组成和晶体结构．结果表明，所合成的晶体属三斜晶系，Pi空间群，a=0．51146（6）nm，b=0．70640（8）nm，c=1．326410（15）nm，a=81．7770（10）°，β=86．361（2）°，γ=76．3970（10）°，F（000）=239，Z=1；最终偏离因子R=0．0264，wR=0．0674．在配合物中，铜离子与来自两个对氯苯氧乙酸根的两个羧基氧原子、两个醚氧原子以及来自两个水分子的氧原子配位，形成变形八面体结构．
|
| 关 键 词： | 对氯苯氧乙酸 铜（Ⅱ）配合物 合成 晶体结构 |
Synthesis and Crystal Structure of [Cu(C8H6ClO3)2(H2O)2] |
| |
| ZHOU Yong-hong.Synthesis and Crystal Structure of [Cu(C8H6ClO3)2(H2O)2][J].Chemical Research,2010,21(1):1-4. |
| |
| Authors: | ZHOU Yong-hong |
| |
| Institution: | ZHOU Yong-hong (1. School of Chemistry and Material Science, Huaibei Coal Industry Teacher＇s College, Huaibei 235000, Anhui, China ; 2 Anhui Provincial Key Laboratory of Energetic Materials, Huaibei 235000, Anhui, China) |
| |
| Abstract: | A new metal-organic complex Cu(C8H6ClO3)2(H2O)2](C8H6ClO3=p-chlorophenoxyacetate) 1 has been synthesized by the reaction of characterized by means of single-crystal X-ray diffraction, elemental analysis and infrared spectrometry. It has been found that the complex belongs to 40(8) nm, c = 1.326 410(15) nm, α = 81.777 0(10)°,β = 86.361(2)°,γ = 76.397 0(10)°,V = 0.460 77(8) nm3, Mr = 470.73, Dc = 1.696 g/cm3, F(000) = 239, Z = 1; and final R = 0.026 4, wR = 0.067 4 for 1 434 observed reflections (I > 2σ(I)). In terms of the crystal structure, copper ion is six-coordinated with two carboxyl oxygen atoms plus two phenoxyl oxygen atoms of two different p-chlorophenoxyacetate and two oxygen atoms of two water molecules, showing a distorted octahedral geometry. |
| |
| Keywords: | p-chlorophenoxyacetic acid synthesis crystal structure |
| 本文献已被 维普 万方数据 等数据库收录！ |
|
