Electrophilic Copper(II) → Metal(II) Substitution in Gelatin-Immobilized Copper(II) Hexacyanoferrate(II) Matrix Implants |
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| Authors: | O V Mikhailov T B Tatarintseva N I Naumkina T Z Lygina |
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| Institution: | (1) Kazan State Technological University, Kazan, Tatarstan, Russia |
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| Abstract: | Contact of thin layers of gelatin-immobilized copper(II) hexacyanoferrate(II) matrices with aqueous solutions of Co(II), Ni(II), Zn(II), and Cd(II) chlorides results in partial substitution of these ions for Cu(II) to give (dd)-heterobinuclear hexacyanoferrates(II) of copper(II) and the corresponding double-charged ion. |
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