Functionalization of saturated hydrocarbons by aprotic superacids 5. Regioselective carbonylation of propane in an organic solvent initiated by aprotic organic superacids CX4·nAlBr
3 (X = Br,Cl;n = 1 or 2) |
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| Authors: | I S Akhrem A V Orlinkov L V Afanas'eva M E Vol'pin |
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| Institution: | (1) Russian Academy of Sciences, A. N. Nesmeyanov Institute of Organoelement Compounds, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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| Abstract: | Aprotic organic superacids CX4 ·nAlBr3 (X = Br, CI; n = 1 or 2) are effective initiators of carbonylation of propane with CO in an organic solvent at -10 to -20 °C.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1214–1216, May, 1996. |
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| Keywords: | propane carbonylation carbon monoxide aprotic superacids polyhalomethanes aluminum bromide |
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