|
|||||
|
|
Benzylic modifications of meso-alkyl-substituted porphyrins via oxidation with DDQ |
|
| Authors: | Xiaobin Peng Chao GaoYuying Huang Junbiao PengNaoki Aratani Atsuhiro Osuka |
| Institution: | a Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, 381 Wushan Road, Guangzhou 510640, China b Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan |
| Abstract: | The reactions at the benzylic positions of meso-alkyl-substituted porphyrins have been achieved via the reaction with DDQ in the presence of alcohol or water for the first time, and ethenyl porphyrins from methoxylated porphyrins and an acetoxy porphyrin from the hydroxyl porphyrin were prepared. |
| Keywords: | Alkyl porphyrin Benzylic modification DDQ |
| 本文献已被 ScienceDirect 等数据库收录！ | |