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Aerobic oxidative dehydrogenation of benzyl alcohols to benzaldehydes by using a cyclometalated ruthenium catalyst |
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| Authors: | Ayako Taketoshi Xin Ning BehJunpei Kuwabara Take-aki KoizumiTakaki Kanbara |
| Affiliation: | a Tsukuba Research Center for Interdisciplinary Materials Science (TIMS), Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba 305-8573, Japan b Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan |
| Abstract: | The ruthenium(III) complex bearing phenylpyridine as a cyclometalated ligand serves as an efficient catalyst for the aerobic oxidative dehydrogenation of benzyl alcohols to the corresponding benzaldehydes under mild conditions and for the one-pot synthesis of benzonitriles from benzyl alcohols with ammonia. |
| Keywords: | Dehydrogenation Homogeneous catalysis Ruthenium Alcohol Aldehyde |
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