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Synthesis and stability of new spiroaminoborate esters
Authors:Stepanenko Viatcheslav  de Jesús Melvin  Garcia Carmelo  Barnes Charles L  Ortiz-Marciales Margarita
Affiliation:a Department of Chemistry, University of Puerto Rico - Humacao, Call Box 860, Humacao, PR 00792, USA
b Department of Chemistry, University of Missouri - Columbia, 125 Chemistry Building, Columbia, MO 65211, USA
Abstract:New spiroaminoborate esters derived from 1,1-diphenylprolinol, ephedrine, and dihydroquinine with different alkoxy substituents were prepared as stable crystalline compounds and characterized by spectroscopical analysis and specific rotation. The structure of the spiroborate 4 derived from 1,1-diphenylprolinol and dicyclohexyl-1,1′-diol was confirmed by X-ray analysis.
Keywords:Chiral spiroaminoborates   Spiroborates   Nonracemic aminoalcohols   Diols
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