Synthesis and stability of new spiroaminoborate esters |
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Authors: | Stepanenko Viatcheslav de Jesús Melvin Garcia Carmelo Barnes Charles L Ortiz-Marciales Margarita |
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Affiliation: | a Department of Chemistry, University of Puerto Rico - Humacao, Call Box 860, Humacao, PR 00792, USA b Department of Chemistry, University of Missouri - Columbia, 125 Chemistry Building, Columbia, MO 65211, USA |
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Abstract: | New spiroaminoborate esters derived from 1,1-diphenylprolinol, ephedrine, and dihydroquinine with different alkoxy substituents were prepared as stable crystalline compounds and characterized by spectroscopical analysis and specific rotation. The structure of the spiroborate 4 derived from 1,1-diphenylprolinol and dicyclohexyl-1,1′-diol was confirmed by X-ray analysis. |
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Keywords: | Chiral spiroaminoborates Spiroborates Nonracemic aminoalcohols Diols |
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