Oxidation of Iron and Nickel with 3,5-Di-<Emphasis Type="Italic">tert</Emphasis>-butyl-1,2-benzoquinone in Coordinating Solvents |
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| Authors: | S V Maslennikov I A Aivaz'yan I V Spirina V K Cherkasov V P Maslennikov |
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| Institution: | (1) Research Institute of Chemistry, Lobachevsky Nizhni Novgorod State University, Nizhni Novgorod, Russia;(2) Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhni Novgorod, Russia |
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| Abstract: | The final products of oxidation of iron and nickel with 3,5-di-tert-butyl-1,2-benzoquinone in DMSO were identified, and the formal-kinetics relationships of the process were elucidated. The apparent equilibrium constants, enthalpies, and entropies of adsorption of the reactants on the metal surfaces and the rate constants and activation energies of the reactions were determined. |
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