Novel intermolecular carbon radical addition to a nitrone: asymmetric synthesis of alpha-amino acids |
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| Authors: | Ueda Masafumi Miyabe Hideto Teramachi Masako Miyata Okiko Naito Takeaki |
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| Institution: | Kobe Pharmaceutical University, Motoyamakita, Higashinada, Kobe 658-8558, Japan. |
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| Abstract: | A nitrone was used as a synthetically useful radical acceptor in carbon-carbon bond-forming radical reactions; the intermolecular addition of alkyl radicals to chiral glyoxylic nitrone was studied; a high degree of stereocontrol in radical addition to glyoxylic nitrone was achieved to provide a new method for asymmetric synthesis of alpha-amino acids. |
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