Molecular recognition. Electrostatic effects in supramolecular self-assembly |
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Authors: | Crowley James D Goshe Andrew J Bosnich B |
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Affiliation: | Department of Chemistry, The University of Chicago, 5735 South Ellis Avenue, Chicago, Illinois 60637, USA. |
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Abstract: | A di-positively charged metal-based receptor is shown to form 1:1 or 2:1 association complexes with rigid, linear two-site guests depending on the site separation, suggesting that electrostatic repulsion controls the association nuclearity. |
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