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Molecular recognition. Electrostatic effects in supramolecular self-assembly
Authors:Crowley James D  Goshe Andrew J  Bosnich B
Institution:Department of Chemistry, The University of Chicago, 5735 South Ellis Avenue, Chicago, Illinois 60637, USA.
Abstract:A di-positively charged metal-based receptor is shown to form 1:1 or 2:1 association complexes with rigid, linear two-site guests depending on the site separation, suggesting that electrostatic repulsion controls the association nuclearity.
Keywords:
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