A novel three-dimensional coordination polymer constructed with mixed-valence dimeric copper(I,II) units |
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| Authors: | Tong Ming-Liang Li Li-Jun Mochizuki Katsunori Chang Ho-Chol Chen Xiao-Ming Li Ying Kitagawa Susumu |
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| Affiliation: | Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan. |
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| Abstract: | A novel three-dimensional coordination polymer with a mixed-valence localized copper(I,II) dimeric unit, [Cu2(4-pya)3]n (4-pya = 4-pyridinecarboxylate), was hydrothermally synthesized via a simultaneous in-situa redox and hydrolysis reaction of Cu(II) and 4-cyanopyridine and crystallographically characterized to be a twofold interpenetrated three-dimensional coordination network with a cubic [Cu16(4-pya)12] building unit. |
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