C-H activation of imidazolium salts by Pt(0) at ambient temperature: synthesis of hydrido platinum bis(carbene) compounds |
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Authors: | Duin Marcel A Clement Nicolas D Cavell Kingsley J Elsevier Cornelis J |
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Affiliation: | Institute of Molecular Chemistry, Organometallic and Coordination Chemistry, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV, Amsterdam, The Netherlands. |
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Abstract: | A zerovalent platinum(carbene) complex with two monoalkene ligands, which is able to activate C-H bonds of imidazolium salts at room temperature to yield isolable hydrido platinum(II) bis(carbene) compounds, has been synthesised for the first time. |
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