Dioxygen activation by a dinuclear nickel thiolate complex: structural characterization of the ligand oxidized product |
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| Authors: | Harrop Todd C Olmstead Marilyn M Mascharak Pradip K |
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| Institution: | Department of Chemistry and Biochemistry, University of California, Santa Cruz, CA 95064, USA. |
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| Abstract: | A (mu-SR)2-nickel(II) dimer derived from a ligand with carboxamido nitrogen and thiolato sulfur donors reacts with O2 to afford an oxidized product in which phenyl groups of the ligand frames are oxidized to nickel-bound phenolates. |
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