三元共聚液晶聚酯酰亚胺/PET共混体系结构与性能研究

通过熔融共混的方式,将实验室自行设计合成的三元共聚热致液晶聚酯酰亚胺(PPDI)与聚对苯二甲酸乙二酯(PET)进行共混,制备一系列不同液晶聚合物含量的共混体系.采用示差扫描量热仪(DSC)、广角X-射线衍射仪(WAXD)和动态力学性能分析仪(DMA)对共混体系的结构与性能进行表征.结果表明,共混体系中两组份之间具有良好...

STRUCTURE AND PROPERTY STUDIES OF LIQUID CRYSTALLINE POLY ( ESTER IMIDE)/PET BLENDS

The effects of terpolymer liquid crystalline poly(ester imide)(PPDI) on the structure and properties of its blend with semicrystalline polymer,poly(ethylene terephthalate)(PET) were studied.The PPDI was synthesized by our lab.The blend systems were prepared by melt blendinga,nd the content of PPDI ranged from 0 /100 to 10 /90.Differential scanning calorimetry(DSC),wide-angle X-ray diffraction(WAXD) and dynamic mechanical property analysis(DMA) were used to study the crystalline behavior,crystalline structure and dynamic mechanical properties of the blend system,as well as the miscibility of PPDI and PET.Results showed that the addiction of liquid crystalline terpolymer PPDI had strong effect on the crystalline behavior and crystalline structure of PET,which acted as heterogeneous nuclear agentst,herefore increasing the initial crystallization point and crystallization rate of PET,and was of benefit to the increase of the degree of crystallinity and the perfection of crystallization.The blend systems show only one glass transition temperature(Tg),and the Tgs are much higher than the theoretical results calculated by using Fox equation.Dynamic mechanical properties showed that storage modulus of the blend systems was higher than that of PET,and increased with the content of PPDI.These mean that PPDI has a reinforcing effect on PET.The thermal stability of the blend systems is a little higher than that of pure PET.