Application of the Prigogine-Flory-Patterson theory part I. Mixtures ofn-alkanes with bicyclic compounds,benzene, cyclohexane andn-hexane |
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| Authors: | T M Letcher R C Baxter |
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| Institution: | (1) Department of Chemistry, Rhodes University, 6140 Grahamstown, South Africa |
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| Abstract: | The Prigogine-Flory-Patterson theory of liquid mixtures has been applied to the H
m
E
and V
m
E
for binary mixtures of an n-alkane with decalin, bicyclohexyl, tetralin, cyclohexylbenzene, benzene, cyclohexane and n-hexane. Furthermore the Prigogine-Flory theory has been used to predict activity coefficients at infinite dilution from the experimentally determined H
m
E
at 25°C and at finite concentrations for n-hexane and n-heptane with decalin, bicyclohexyl, tetralin and cyclohexylbenzene. |
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| Keywords: | Prigogine-Flory-Patterson theory benzene cyclohexane n-hexane n-heptane decalin bicyclohexyl tetralin cyclohexylbenzene excess molar enthalpies excess molar volumes activity coefficients at infinite dilution Prigogine-Flory theory |
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