| N-(2,3-二甲氧基苯基亚甲基)-4-硝基苯胺的合成及晶体结构 |
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| 引用本文： | 朱瑞涛,相永刚,李文娟. N-(2,3-二甲氧基苯基亚甲基)-4-硝基苯胺的合成及晶体结构[J]. 光谱实验室, 2012, 29(3): 1809-1811 |
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| 作者姓名： | 朱瑞涛 相永刚 李文娟 |
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| 作者单位： | 太原师范学院化学系 太原市黄陵路19号 030031 |
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| 基金项目： | 山西省科学技术发展计划项目 |
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| 摘 要： | 室温下由2,3-二甲氧基苯甲醛、4-硝基苯胺缩合反应制成了N-(2,3-二甲氧基苯基亚甲基)-4-硝基苯胺(1)。X射线单晶衍射仪测定了(1)的晶体结构,属于单斜晶系,P2(1)/c空间群,晶胞参数为:a=1.41919(14)nm,b=1.39745(12)nm,c=0.69710(7)nm,α=90°,β=102.365(1)°,γ=90°,V=1.3505(2)nm3,F(000)=600,Mr=286.28,Dc=1.408 g/cm3,μ=0.104 mm-1,R1=0.1138,ωR2=0.2621。
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| 关 键 词： | N-(2,3-二甲氧基苯基亚甲基)-4-硝基苯胺 合成 晶体结构 |
Synthesis and Crystal Structure of N- (2,3-Dimethoxybenzylidene)-4-Nitroaniline |
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| ZHU Rui-Tao , XIANG Yong-Gang , LI Wen-Juan. Synthesis and Crystal Structure of N- (2,3-Dimethoxybenzylidene)-4-Nitroaniline[J]. Chinese Journal of Spectroscopy Laboratory, 2012, 29(3): 1809-1811 |
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| Authors: | ZHU Rui-Tao XIANG Yong-Gang LI Wen-Juan |
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| Affiliation: | ZHU Rui-Tao XIANG Yong-Gang LI Wen-Juan(Department of Chemistry,Taiyuan Normal University,Taiyuan 030031,P.R.China) |
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| Abstract: | The title compound,N-(2,3-dimethoxybenzylidene)-4-nitroaniline(1),was prepared by a condensation reaction between 2,3-dimethoxybenzaldehyde and 4-nitroaniline at room temperature.The structure of 1 was characterized.The crystal of 1 belongs to the monoclinic system and space group P2(1)/c,and cell parameters were as follows:a=1.41919(14)nm,b=1.39745(12)nm,c=0.69710(7)nm,α=90°,β=102.365(1)°,γ=90°,V=1.3505(2)nm3,F(000)=600,Mr=286.28,Dc=1.408g/cm3,μ=0.104mm-1,R1=0.1138,ωR2=0.2621. |
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| Keywords: | N-(2,3-Dimethoxybenzylidene)-4-Nitroaniline Synthesis Crystal Structure |
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