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Room-Temperature Ionic Liquids: For a Difference in the Supramolecular Synthesis
Authors:V. R. Pedireddi  Manishkumar R. Shimpi  J. V. Yakhmi
Affiliation:1. Division of Organic Chemistry, Solid State & Supramolecular Structural Chemistry Lab, National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411 008, India;2. Technical Physics & Prototype Engineering Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085, India
Abstract:Cu(I) and Ni(II) coordination polymers with 4,4′-bipyridine and 2,2′-bipyridine, respectively, that have been synthesized from an ionic liquid (1-ethyl-3-methylimidazolium tetrafluoroborate) gave different coordination environment and supramolecular networks than the corresponding synthesis from the other solvents. The resultant complexes were characterized by single crystal x-ray diffraction methods.
Keywords:ionic liquids  supramolecular
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