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Conducting Polymer Coated DNA
Authors:Yosef Bardavid  Alexander B Kotlyar  Shlomo Yitzchaik
Institution:1. Department of Inorganic and Analytical Chemistry, the Hebrew University of Jerusalem, Jerusalem 91904 Israel;2. Department of Biochemistry, George S. Wise Faculty of Life Sciences, Tel Aviv University, Ramat Aviv, 69978 Israel
Abstract:Gold electrode was modified with a 4-aminothiophenol layer (4-ATPh) to immobilize DNA. The immobilized DNA served as a template for the alignment of positively charged anilinium ions. The electrochemical oxidation of the anilinium ions resulted in wrapping of the DNA with polyaniline. This polyaniline coated DNA was characterized by cyclic voltammetry (CV), impedance spectroscopy and UV-VIS absorption spectroscopy.
Keywords:DNA  electropolymerization  molecular wires  monolayers  nanoelectronics  polyaniline
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