Pd-catalyzed allylic substitution using nucleophilic N-heterocyclic carbene as a ligand |
| |
Authors: | Sato Yoshihiro Yoshino Taro Mori Miwako |
| |
Institution: | Graduate School of Pharmaceutical Sciences, Hokkaido University, Sapporo 060-0812, Japan. |
| |
Abstract: | A nucleophilic N-heterocyclic carbene has been successfully used in a Pd(0)-catalyzed allylic substitution for the first time. It was found that allylic substitution with a soft nucleophile using a Pd-carbene catalyst proceeds via retention of configuration, the stereochemical reaction pathway being the same as that of the reaction using a Pd-phosphine complex. reaction--see text] |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|