Free base meso-tetraaryl-morpholinochlorins and porpholactone from meso-tetraaryl-2,3-dihydroxy-chlorin |
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Authors: | McCarthy Jason R Jenkins Hilary A Brückner Christian |
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Institution: | Department of Chemistry, University of Connecticut, Storrs, CT 06269-3060, USA. |
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Abstract: | meso-Tetraaryl-2,3-dihydroxychlorins (1) were converted in one step to the novel free base macrocycles meso-tetraaryl-2,3-dialkoxy-2a-oxa-2a-homoporphyrins (morpholinochlorins, 3). Their bathochromically shifted chlorin-type UV-vis spectra indicate the presence of a nonplanar chromophore. The structure of meso-tetratolyldiethoxymorpholinochlorin (3b), as determined by X-ray crystallography, was found to be largely planar, suggesting significant conformational flexibility of these macrocycles. Oxidation of diol 1 with MnO(4)(-) generates known porpholactone 4 in high yields. reaction--see text] |
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