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| 2，3－二苯基－1，4，6－三氮杂二环[3.3.1]－2－壬烯单盐酸盐的合成及晶体结构 | |
| 引用本文： | 王虎林,薛岗林,徐媛,王兰英,王文亮,胡怀民.2，3－二苯基－1，4，6－三氮杂二环[3.3.1]－2－壬烯单盐酸盐的合成及晶体结构[J].有机化学,2003,23(7):710-713. |
| 作者姓名： | 王虎林 薛岗林 徐媛 王兰英 王文亮 胡怀民 |
| 作者单位： | 1. 西北大学化学系陕西省物理无机化学重点实验室,西安,710069 2. 陕西师范大学化学系,西安,710058 3. 中国科学院化学研究所,北京,100080 |
| 基金项目： | 陕西省化学反应工程重点实验室开放基金,陕西省教委专项基金(No.99JK105) |
| 摘 要： | 在ZrOCl_2的存在下,二乙烯三氨与联苯甲酰在甲醇中回流得到2,3－二苯基 －1,4,6－三氮杂二环3.3.1]－2－壬烯单盐酸盐。对其进行了~1H NMR,IR和 UV-vis谱表征及X射线单晶衍射结构分析。晶体属单斜晶系,P2_1/c空间群,晶胞 参数为：a=1.69341(6)nm,b=0.77564(3)nm,c=1.21000(4)nm,β=96.1880(10)° ,Z=4,D_c=1.319g·cm~(-3)。该化合物是一非平面型具有部分不饱和键的氮杂桥 二环化合物,两个六元环中,与苯环连接的六元环为半椅式构型,另一六元环为椅 式构型。 |
| 关 键 词： | 氮杂环化合物 壬烯 P 晶体结构 质子磁共振谱法 红外分光光度法 紫外分光光度法 X射线衍射分析 |
| 修稿时间： | 2002年7月19日 |
Synthesis and Crystal Structure of 2,3-Dibenzo-1,4,6-triazabicyclo [3.3.1]-2-nonenemonomuriate |
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| WANG,Hu-Lin XUE,Gang-Lin XU,Yuan WANG,Lan-Ying WANG,Wen-Liang HU,Huai-Min.Synthesis and Crystal Structure of 2,3-Dibenzo-1,4,6-triazabicyclo [3.3.1]-2-nonenemonomuriate[J].Chinese Journal of Organic Chemistry,2003,23(7):710-713. | |
| Authors: | WANG Hu-Lin XUE Gang-Lin XU Yuan WANG Lan-Ying WANG Wen-Liang HU Huai-Min |
| Institution: | Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry, Northwest University;Department of Chemistry, Shaanxi Normal University;Institute of Chemistry, Chinese Academy of Sciences |
| Abstract: | The azo-cycle compound, 2,3-dibenzo-l, 4,6-triazabicyclo 3.3.1 ] - 2-nonenemonomuriate, was prepared by condensation of benzil with dienthyltriamine in methanol and in the presence of Z1OCI2, and was characterized by !H NMR, IR and UV-vis spectra. Its crystal structure was determined by X-ray diffraction analysis. The crystal belongs to monoclinic system, space group P2j/c, cell parameters: a = 1.69341(6) nm, b = 0.77564(3) nm, c = 1.21000(4) nm, /? = 96.1880(10)°, Z = 4, Dc = 1.319 g- cm"3. The compound is a non-planar aza-bicyclo compound with partial unsaturated bonds. The parent hexatomic ring is a chair conformation and the other six-member ring is a half-chair form. |
| Keywords: | 2 3-dibenzo-1 4 6-triazabicyclo[3 3 1]-2-nonenemonomuriate synthesis crystal structure |
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