Palladium-catalyzed cross-coupling of acetates of Baylis-Hillman adducts and potassium organotrifluoroborates |
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Authors: | Kabalka George W Venkataiah Bollu Dong Gang |
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Affiliation: | Department of Chemistry, The University of Tennessee, Knoxville, Tennessee 37996-1600, USA. kabalka@utk.edu |
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Abstract: | [reaction: see text] The cross-coupling of potassium organotrifluoroborates and acetates of Baylis-Hillman adducts proceeds readily in moderate to excellent yield in the presence of Pd(OAc)(2). The reaction tolerates hindered trifluoroborate salts, and the process is stereoselective. |
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