Reactions of arensulfenamides with olefins in the presence of picric acid |
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| Authors: | N. V. Zyk E. K. Beloglazkina A. V. Mamaeva |
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| Affiliation: | (1) Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899 Moscow, Russian Federation |
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| Abstract: | N-(2- and 4-Nitrophenylthio)morpholines in the presence of equimolar amounts of picric acid enter into the reaction of electrophilic sulfenylation of the C=C norbornene bond to give bi- and tricyclic sulfides. With cyclohexene,trans-2-arylthiocyclohexanol are formed. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1661–1663, August, 1998. |
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| Keywords: | arénsulfenamides picric acid sulfenylation |
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