Design of Phase‐Vanishing Reactions |
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| Authors: | Nathan J. Van Zee Veljko Dragojlovic Prof. Dr. |
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| Affiliation: | 1. Wilkes Honors College, Florida Atlantic University, 5353 Parkside Drive, Jupiter, FL 33458 (USA), Fax: (+1)?561‐799‐8602;2. present address: Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, NY 14853‐1301 (USA) |
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| Abstract: | Phase‐vanishing reactions utilize a perfluorinated solvent as a liquid membrane to separate a substrate and a reagent. Since their introduction less than ten years ago, phase‐vanishing reactions have become a valuable alternative to reactions that require a slow addition of a reagent. A variety of experimental designs allow reactions to be carried out under anhydrous conditions, under photolytic conditions, under solvent‐free conditions, with a gas as a reagent, and under reflux. |
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| Keywords: | experimental designs liquid membranes perfluorinated solvents phase screens synthesis design |
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