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Transition‐Metal‐Catalyzed Synthesis of Hydroxylated Arenes
Authors:Diego A. Alonso Dr.  Carmen Nájera Prof. Dr.  Isidro M. Pastor Dr.  Miguel Yus Prof. Dr.
Affiliation:Organic Chemistry Department and Institute for Organic Synthesis (ISO), Universidad de Alicante, Carretera de San Vicente s/n, Apdo. 99, 03080, Alicante (Spain), Fax: (+34)?965903549
Abstract:An overview of the recent bibliography in the transition‐metal‐catalyzed hydroxylation of aryl derivatives is presented. Two reaction protocols are considered: 1) C? H activation/hydroxylation and, 2) cross‐coupling hydroxylation of aryl halides. The achievements and limitations for both procedures are described taking into consideration different metal catalyst/oxidant combinations.
Keywords:C?H activation  homogeneous catalysis  hydroxylation  oxidation  phenols
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