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Nonenzymatic Electrochemical Glucose Sensor Based on Pt Nanoparticles/Mesoporous Carbon Matrix
Authors:Chang Su  Cheng Zhang  Guoqiang Lu  Chunan Ma
Affiliation:1. State Key Laboratory Breeding Base for Green Chemistry Synthesis Technology, College of Chemical Engineering and materials Science, Zhejiang University of Technology, Caowang Road 18#, Hangzhou, 310014, P.?R. China tel.: +86‐571‐88320253;2. fax: +86‐571‐88320253.
Abstract:A nonenzymatic amperometric sensor for sensitive and selective detection of glucose has been constructed by using highly dispersed Pt nanoparticles supported onto mesoporous carbons (MCs). The Pt nanoparticles/mesoporous carbons (Pt/MCs) composites modified electrode displayed high electrocatalytic activity towards the oxidation of glucose. At an applied potential of 0.1 V, the Pt/MCs electrode has a linear dependence (R=0.996) in the glucose concentration up to 7.5 mM with a sensitivity of 8.52 mA M?1 cm?2. The Pt/MCs electrode has also shown highly resistant toward poisoning by chloride ions and without interference from the oxidation of common interfering species.
Keywords:Mesoporous carbons  Pt nanoparticles  Glucose  Nonenzymatic sensor  Nanoparticles  Sensors
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