Nonenzymatic Electrochemical Glucose Sensor Based on Pt Nanoparticles/Mesoporous Carbon Matrix |
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Authors: | Chang Su Cheng Zhang Guoqiang Lu Chunan Ma |
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Affiliation: | 1. State Key Laboratory Breeding Base for Green Chemistry Synthesis Technology, College of Chemical Engineering and materials Science, Zhejiang University of Technology, Caowang Road 18#, Hangzhou, 310014, P.?R. China tel.: +86‐571‐88320253;2. fax: +86‐571‐88320253. |
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Abstract: | A nonenzymatic amperometric sensor for sensitive and selective detection of glucose has been constructed by using highly dispersed Pt nanoparticles supported onto mesoporous carbons (MCs). The Pt nanoparticles/mesoporous carbons (Pt/MCs) composites modified electrode displayed high electrocatalytic activity towards the oxidation of glucose. At an applied potential of 0.1 V, the Pt/MCs electrode has a linear dependence (R=0.996) in the glucose concentration up to 7.5 mM with a sensitivity of 8.52 mA M?1 cm?2. The Pt/MCs electrode has also shown highly resistant toward poisoning by chloride ions and without interference from the oxidation of common interfering species. |
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Keywords: | Mesoporous carbons Pt nanoparticles Glucose Nonenzymatic sensor Nanoparticles Sensors |
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