Synthesis of a GaN Cage Compound with a Hydrazinetetraide Fragment, [N?N]4−, Stabilised by Six Gallium Atoms |
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| Authors: | Prof Dr Werner Uhl Babak Rezaeirad Dr Marcus Layh Elke Hagemeier Prof Dr Ernst‐Ulrich Würthwein Dr Nugzar Ghavtadze Dr Istemi Kuzu |
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| Institution: | 1. Institut für Anorganische und Analytische Chemie der Universit?t Münster, Corrensstrasse 30, 48149 Münster (Germany), Fax: (+49)?251‐8336660;2. Organisch‐Chemisches Institut der Universit?t Münster, Corrensstrasse 40, 48149 Münster (Germany);3. Fachbereich Chemie, Philipps‐Universit?t Marburg, Hans‐Meerwein‐Stra?e, 35032 Marburg (Germany) |
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| Abstract: | Thermolysis of the bicyclic gallium hydrazide (GaMe2)4(NH? NMe)(NH? NHMe)2] ( 1 ) yielded the unique cage compound (GaMe)4(GaMe2)4(N2)(NH? NMe)4] ( 2 ). Compound 2 contains a remarkable hydrazinetetraide moiety, N? N]4?, as the central structural motif which is stabilised by coordination to six gallium atoms. |
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| Keywords: | cage compounds gallium hydrazides nitrogen pernitride |
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