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Dendronizing and Metalating trans‐2 C60 Tetraaryl Porphyrins—A Versatile Approach Toward Water‐Soluble Donor–Acceptor Conjugates |
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| Authors: | Dipl‐Chem Michaela Ruppert Dr Fabian Spänig Dr Mateusz Wielopolski Christof M Jäger Prof?Dr Walter Bauer Prof?Dr Timothy Clark Prof?Dr Andreas Hirsch Prof?Dr Dirk M Guldi |
| Institution: | 1. Department of Chemistry and Pharmacy and Interdisciplinary Center for Molecular Materials (ICMM), Friedrich‐Alexander‐Universit?t Erlangen‐Nürnberg, Henkestrasse 42, 91054 Erlangen (Germany), Fax: (+49)?9131‐852‐6864;2. Department of Chemistry and Pharmacy and Interdisciplinary Center for Molecular Materials (ICMM), Friedrich‐Alexander‐Universit?t Erlangen‐Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany), Fax: (+49)?9131‐852‐7340;3. Department of Chemistry and Pharmacy and Interdisciplinary Center for Molecular Materials (ICMM), Friedrich‐Alexander‐Universit?t Erlangen‐Nürnberg, N?gelsbacherstrasse 25, 91052 Erlangen (Germany), Fax: (+49)?9131‐852‐6565 |
| Abstract: | We have realized for the first time a series of truly water‐soluble and tightly coupled porphyrin/C60 electron‐donor–acceptor conjugates in which the charge separation and charge recombination dynamics are controlled by modifying the nature of the dendrimer and/or the choice of the central metal atom. |
| Keywords: | charge transfer fullerenes molecular modeling porphyrinoids |