Electrolytes in etching of latent tracks of heavy ions in polyethylene terephthalate |
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Authors: | A I Vilensky Yu K Kochnev S V Vlasov B V Mchedlishvili |
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Institution: | (1) Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 117333, Russia;(2) Lomonosov State Academy of Fine Chemical Technology, ul. Vernadskogo 86, Moscow, 117571, Russia |
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Abstract: | Previously unknown features of etching of polyethylene terephthalate, latent tracks of multiply charged accelerated ions in it, and track membrane pore formation are considered. It was found that K ions (in the form of KCl salt) in a KOH solution enhance etching of both initial polyethylene terephthalate and tracks. Ba2+ ions enhancing etching of initial polymer significantly inhibit etching of tracks. It is assumed that etching inhibition is associated with Ba2+ ion adsorption on track active centers. The features detected are used to fabricate track membranes with thin selective layer. |
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