| Total Synthesis of L-Oleandrose and L-Cymarose from an Achiral Precursor, Methyl Sorbata |
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| 作者姓名： | Xi Ying ZHAO Machiko ONO Hiroyuki AKITA Yu Ming CHI |
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| 作者单位： | School of Pharmaceutical Sciences Toho University Chiba 274-8510 Japan，School of Pharmaceutical Sciences Toho University Chiba 274-8510 Japan |
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| 摘 要： | Rare monosaccharides are important structural components of antibiotics and cardiac glycosides1,2, and functionalized monosaccharides continue to be of interest as intermediates in natural product synthesis3,4. The 2,6-dideoxy sugar L-oleandrose 1 occurs …
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| 关 键 词： | 甲基山梨酸酯 合成 L-夹竹桃糖 抗生素 配醣 |
| 收稿时间： | 2005-11-23 |
Total Synthesis of L-Oleandrose and L-Cymarose from an Achiral Precursor, Methyl Sorbata |
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| Xi Ying ZHAO Machiko ONO Hiroyuki AKITA Yu Ming CHI.Total Synthesis of L-Oleandrose and L-Cymarose from an Achiral Precursor, Methyl Sorbata[J].Chinese Chemical Letters,2006,17(6):730-732. |
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| Authors: | Xi Ying ZHAO Machiko ONO Hiroyuki AKITA Yu Ming CHI |
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| Abstract: | 2,6-Dideoxy sugars L-oleandrose 1 and L-cymarose 2, the key carbohydrate of antibiotics and cardiac glycosides, were synthesized by an efficient synthetic method from an achiral precursor, methyl sorbate. |
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| Keywords: | L-Oleandrose L-cymarose methyl sorbate |
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