Spin polarization transfer during the addition reaction of phosphorus radicals to simple olefins in solution |
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| Authors: | K Akiyama M C Depew J K S Wan |
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| Institution: | 1. The Chemical Research Institute of Non-Aqueous Solutions, Tohoku University, 980, Sendai, Japan
2. Department of Chemistry, Queen’s University, K7L 3N6, Kingston, Ontario, Canada
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| Abstract: | A CIDEP study of the radical adducts formed by addition of phosphonyl radicals to several unsaturated organic compounds is described. The complicated time-resolved ESR spectra obtained for these adducts were interpreted on the basis of competing chemical and physical processes involved in polarization transfer to the secondary radicals produced. This is a novel example illustrating for the first time radical pair polarization transfer in solution. |
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