The N-donor stabilised cyclotriphosphazene hexacation [P3N3(DMAP)6]6+ |
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| Authors: | Boomishankar Ramamoorthy Ledger Joanne Guilbaud Jean-Baptiste Campbell Neil L Bacsa John Bonar-Law Richard Khimyak Yaroslav Z Steiner Alexander |
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| Institution: | Department of Chemistry, University of Liverpool, Crown Street, Liverpool, UK. |
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| Abstract: | The cyclotriphosphazene P(3)N(3)Cl(6) reacts with six equivalents of DMAP (4-(dimethylamino)pyridine) in superheated chloroform to form crystals of composition P(3)N(3)(DMAP)(6)]Cl(6).19CHCl(3) comprising P(3)N(3)(DMAP)(6)](6+) ions, which host five chloride ions in basket-type cavities on either side of the ring and at equatorial positions via tetradentate ortho-H-donor arrangements. |
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