Field-induced metamagnetic transition in the Fe(III)-Mn(III) bimetallic chain built by a new cyanide-bearing Fe(III) precursor |
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| Authors: | Kim Jae Il Yoo Houng Sik Koh Eui Kwan Hong Chang Seop |
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| Institution: | Department of Chemistry, Korea University, Seoul 136-713, Korea. |
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| Abstract: | The use of a new precursor, mer-Fe(mpzcq)(CN)3]- (1), produced a dimeric molecule, Fe(mpzcq)(CN)3]Mn(salen)(H2O)] x H2O (2), and a one-dimensional zigzag chain, Fe(mpzcq)(CN)3]Mn(salcy)] x MeOH x MeCN (3). Antiferromagnetic couplings are operating between magnetic centers through CN ligands, and a field-induced metamagnetic transition is observed in 3. |
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