| Oxidative Cross-Coupling Reactions between Two Nucleophiles |
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| 作者姓名： | Lijun Lu Hao Li Aiwen Lei |
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| 作者单位： | Institute for Advanced Studies（IAS） |
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| 基金项目： | This work was supported by the National Natural Science Foundation of China(No.22031008);the Science Foundation of Wuhan(No.2020010601012192). |
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| 摘 要： | What is the most favorite and original chemistry developed in your research group?Oxidative Cross-Coupling-The chemistry between two"nucleophiles".How do you get into this specific field?Could you please share some experiences with our readers?My first contact with palladium chemistry was the halopalladation of acetylene in 1998.Then I worked on palladium enolate and found it could initiate a transmetalation reaction.Until 2006,I found that desyl chloride(a halogenated hydrocarbon)showed different reactivity with orga no metallic reagents due to the halophilic and oxyphilic properties,thus we achieved the cross-coupling between two orga no metallic reagents.
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| 关 键 词： | Oxidative cross-coupling Oxidation-induced Reaction mechanisms PHOTOCHEMISTRY ELECTROCHEMISTRY |
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