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流动注射在线液-液萃取-ICP-AES测定土壤和化探样品中痕量铌和钽
引用本文:艾军,汤志勇.流动注射在线液-液萃取-ICP-AES测定土壤和化探样品中痕量铌和钽[J].光谱学与光谱分析,2001,21(5):658-660.
作者姓名:艾军  汤志勇
作者单位:1. 武汉化工学院制药系,
2. 中国地质大学材料科学与化学工程学院,
基金项目:本文受国土资源部科技项目资助(编号950561-2)
摘    要:应用流动注射在线萃取技术将Nb,Ta萃入甲基异丁酮(MIBK)和磷酸三丁脂(TBP)混合溶剂直接进行ICP-AES测定.研究了流动注射在线萃取-电感耦合等离子体原子发射光谱法测定土壤和化探样品中Nb和Ta的实验条件、流路参数、酸度条件的选择,考察了共存元素的干扰.采样速率为20样@h-1,RSD(n=10)为Nb4.5%;Ta5.1%,测定检出限(K=3)为Nb0.5ng@mL-1;Ta0.8ng@mL-1.方法操作简便、快速,经对国家一级标准物质分析,结果与推荐值一致.

关 键 词:液液萃取  流动注射  电感耦合  等离子体原子发射光谱法      化探样品  土壤  痕量分析
文章编号:1000-0593(2001)05-0658-03
修稿时间:2001年3月15日

On-line Determination of Niobium and Tantalum in Soil and Geochemical Exploration Samples by Inductively Coupled Plasma Atomic Emission Spectrometry with Solvent Extraction Flow Injection
J Ai,Z Y Tang.On-line Determination of Niobium and Tantalum in Soil and Geochemical Exploration Samples by Inductively Coupled Plasma Atomic Emission Spectrometry with Solvent Extraction Flow Injection[J].Spectroscopy and Spectral Analysis,2001,21(5):658-660.
Authors:J Ai  Z Y Tang
Institution:Department of Pharacy, Wuhan Institute of Chemical Technology, Wuhan 430073, China.
Abstract:A new method for the determination of trace niobium and tantalum in soil and geochemical exploration samples by inductively coupled plasma atomic emission spectrometry with solvent extraction flow injection was proposed. The niobium and tantalum were extracted with the mixed solvent of MIBK and TBP at 1 mol.L-1 HF and 4 mol.L-1 H2SO4. Experiment conditions and manifold parameters were investigated in detail. The detection limits were 0.5 x 10(-12) g.L-1 and 0.8 x 10(-12) g.L-1. The proposed method was rapid, simple and accurate, it has been applied to the determination of trace niobium and tantalum in national standard samples. The results were in good agreement with certified values with precisions of 4.5% and 5.1% RSD (n = 10). The sample throughput for niobium and tantalum is 20.h-1.
Keywords:Flow injection  Inductively coupled plasma atomic emission spectrometry  Niobium  Tantalum
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