Methanol triggered ligand flip isomerization in a binuclear copper(I) complex and the luminescence response |
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| Authors: | Li Yang-Juan Deng Zhi-Ying Xu Xue-Fei Wu Hua-Bin Cao Ze-Xing Wang Quan-Ming |
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| Affiliation: | State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, PR China. |
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| Abstract: | Methanol drives the blue emissive complex, [Cu(2)(dppy)(3)(MeCN)](BF(4))(2) (dppy = diphenylphosphino-pyridine), with a head-to-tail arrangement of the three bridging phosphine ligands to convert to its linkage isomer (head-to-head, green emissive) in the solid state, and the transformation could be reversibly realized through recrystallization in different solvents. |
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