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Novel Zn(Ⅱ) ladder-like coordination polymer constructed from designed ferrocenyl ligand
作者姓名:Hai  Fang  Zhang  Zi  Feng  Li  Gang  Li  Li  Peng  Wang  Jia  Bin  Li  Guang  Jian  Mei
作者单位:Department of Chemistry, Zhengzhou University, Zhengzhou 450052, China
基金项目:国家自然科学基金 , 教育部重点计划 , Scientific Research Foundation for the Returned Overseas Chinese Scholars of Chinese Ministry of Education , Student Innovation Experimental Item of Zhengzhou University  
摘    要:Reaction of Zn(NO3)2·6H2O with 3-(4-carboxylphenylamino)-l-ferrocenyl-2-butylen-l-one (HL) and 4,4′-bipyfidine (4,4′- bipy) in methanol solution resulted in a novel ladder-like coordination polymer {Zn2L2(μ2-L)2(4,4′-bipy)2]·MeOH}n (1). Its crystal structure, thermal and electrochemical properties are presented.

关 键 词:二茂铁甲醛  合成  聚合体  配合体
收稿时间:21 March 2008. 

Novel Zn(II) ladder-like coordination polymer constructed from designed ferrocenyl ligand
Hai Fang Zhang Zi Feng Li Gang Li Li Peng Wang Jia Bin Li Guang Jian Mei.Novel Zn(II) ladder-like coordination polymer constructed from designed ferrocenyl ligand[J].Chinese Chemical Letters,2008,19(12):1499-1503.
Authors:Hai Fang Zhang  Zi Feng Li  Gang Li  Li Peng Wang  Jia Bin Li  Guang Jian Mei
Institution:Department of Chemistry, Zhengzhou University, Zhengzhou 450052, China
Abstract:Reaction of Zn(NO3)2.6H2O with 3-(4-carboxylphenylamino)-1-ferrocenyl-2-butylen-1-one (HL) and 4,4'-bipyridine (4,4'-bipy) in methanol solution resulted in a novel ladder-like coordination polymer {Zn2L2(μ2-L)2(4,4'-bipy)2].MeOH}n (1). Its crystal structure, thermal and electrochemical properties axe presented.
Keywords:Zinc(R)  Sturcture  Coordination polymer    Designed ferrocenyl figand  Thermal and electrochemical properties
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