Relations between the probability of heterogeneous-homogeneous radical-chain mechnism and oxygen bond energy in oxide catalysts |
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| Authors: | G I Golodets |
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| Institution: | (1) Institute of Physical Chemistry, 252028 Kiev, USSR |
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| Abstract: | Transition metal oxides increase the first ignition limit for 2 H2+O2 mixture (P1) due to their reduction by H atoms, which leads to chain termination. The dependence of P1 on the metal-oxygen bond energy and also on the heterogeneous catalytic activity of oxides has been established.
                    (P1)       -,    .    P1  -, P1 - .
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