Thermodynamic activation functions of viscous flow of non-polar liquids |
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Authors: | J. Kotas M. Valešová |
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Affiliation: | (1) Chemopetrol, Research Institute of Macromolecular Chemistry, Tkalcovská 2, CS-65649 Brno, CSSR |
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Abstract: | The thermodynamic activation function of viscous flow may be determined from the expression for the pre-exponential factor in the Eyring relationship (the viscosity coefficient), which is a function of density and relative permittivity, together with the thermal dependence of the viscosity coefficient. This method of determination is demonstrated for a series of n-alkanes C6–C20.List of symbols A, B, C parameters in empirical viscosity-temperature dependence - E molecular bond energies of liquid calculated from heat of evaporation in vacuum - Ev viscous flow activation energy - G activation Gibbs function of viscous flow - Hv heat of evaporation - Hvb heat of evaporation at boiling point - H viscous flow activation enthalpy - k Boltzmann constant - m weight of molecule - M relative molecular weight - NA Avogadro constant - q total number of bonds in one mole of liquid - R gas constant - Sid entropy of one mole of compound in ideal gas state - Ssat entropy of one mole of compound in saturated vapour state - S activation entropy of viscous flow - T absolute temperature - Tc critical temperature - Tr reduced temperature - Tc critical volume - Tf free volume of liquid per molecule - V0 molar volume of molecules - Vm molar volume of liquid - relative permittivity - viscosity - density - r reduced density |
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Keywords: | Free enthalpy enthalpy entropy of activation viscous flow non-polar liquid |
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