| 几种对称镍卟啉配合物的合成、表征和电化学性质 |
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| 引用本文： | 康敬万 耿再新. 几种对称镍卟啉配合物的合成、表征和电化学性质[J]. 应用化学, 1999, 16(3): 73-75 |
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| 作者姓名： | 康敬万 耿再新 |
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| 作者单位： | 西北师范大学化学研究所 |
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| 摘 要： | 卟啉试剂是一类重要的离子配位显色剂，在生物体中具有重要作用．作为自然界存在的金属卟啉之一，镍卟啉的电化学研究具有化学和生物学意义．四对羟基苯基卟啉合成已有不少报道［１，２］，但产率较低，只有１０％左右．Ｌｉｎｄｓｅｙ等发现用ＢＦ３作催化剂，在ＣＨ２Ｃ...
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| 关 键 词： | 卟啉镍配合物，合成，表征，电化学性质 |
Synthesis and Electrochemical Behavior of Symmetrical Nickel Porphyrins |
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| Kang Jingwan,Geng Zaixin,Lu Xiaoquan,Zhou Xibin,Gao Jinzhang. Synthesis and Electrochemical Behavior of Symmetrical Nickel Porphyrins[J]. Chinese Journal of Applied Chemistry, 1999, 16(3): 73-75 |
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| Authors: | Kang Jingwan Geng Zaixin Lu Xiaoquan Zhou Xibin Gao Jinzhang |
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| Affiliation: | Kang Jingwan,Geng Zaixin,Lu Xiaoquan*,Zhou Xibin,Gao Jinzhang |
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| Abstract: | Tetra(4hydroxyphenyl)porphyrin(THPPH2) was synthesized by condensation of 4hydroxybenzaldehyde and pyrrole in DMF using anhydrous AlCl3 as catalyst without neccessity to use inert gas for protection. Its nickel complex(THPPNi) and Ni mesotetra(4benzoxyphenyl)porphyrin(TBOPPNi), Ni mesotetra porphyrin(TCMOPPNi) were also prepared. Their structures were ascertained by elemental analysis, visible spectrum, IR and 1H NMR measurements. The electrochemical property of TCMOPPNi has been investigated in DMSO by cyclic voltammetry and differential pulse voltammetry. |
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| Keywords: | nickel porphyrin synthesis characterization electrochemical property |
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