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H2S对丙炔醇在Fe/H2SO4体系中缓蚀作用的影响
引用本文:阎丽静,林海潮,吴维文. H2S对丙炔醇在Fe/H2SO4体系中缓蚀作用的影响[J]. 应用化学, 1999, 16(3): 1-0
作者姓名:阎丽静  林海潮  吴维文
作者单位:中科院金属腐蚀与防护研究所,沈阳金属所,中国科学院金属腐蚀与防护研究所
摘    要:铁腐蚀;硫化氢;H2S对丙炔醇在Fe/H2SO4体系中缓蚀作用的影响

关 键 词:铁腐蚀  硫化氢  H2S对丙炔醇在Fe/H2SO4体系中缓蚀作用的影响  
收稿时间:2009-06-29
修稿时间:2009-06-29

Effect of Hydrogen Sulfide on the Inhibition Action of Propargyl Alcohol in Fe/H2SO4 System
Yan Lijing,Lin Haichao,Wu Weitao. Effect of Hydrogen Sulfide on the Inhibition Action of Propargyl Alcohol in Fe/H2SO4 System[J]. Chinese Journal of Applied Chemistry, 1999, 16(3): 1-0
Authors:Yan Lijing  Lin Haichao  Wu Weitao
Affiliation:Yan Lijing*,Lin Haichao,Wu Weitao
Abstract:The effect of H2S on the inhibition action of propargyl alcohol(PA) in Fe/H2SO4 system has been investigated by electrochemical potentiodynamic and potentiostatic methods. The results showed that PA could inhibit the anodic and cathodic reactions of iron corrosion effectively in H2SO4 solution containing H2S. At low content of PA the inhibition efficiency decreased with the increase of H2S content due to the strong interaction of H2S and HS- with Fe. At high content of PA, Fe(HS-)ads is stabilized owing to the hydrogen bonds and electrostatic action, which made the anodic current approach to zero. The interaction between PA and Fe(H2S)ads in this case is weak.
Keywords:iron corrosion  propargyl alcohol  H2S  inhibition effect
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