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双金属复合氧化物的结构与紫外阻隔性能
引用本文:许国志,李蕾,张春英,段雪.双金属复合氧化物的结构与紫外阻隔性能[J].应用化学,1999,16(5):106-0.
作者姓名:许国志  李蕾  张春英  段雪
作者单位:北京轻工业学院,北京化工大学
摘    要:双金属复合氧化物(CLDH)是一类发展迅速的无机层状材料的煅烧产物,在催化、吸附等领域已获长足进展[1],但作为紫外阻隔材料的性能研究尚鲜见报道.本文研究了不同双金属复合氧化物的紫外阻隔性能,结果发现二价金属离子为锌离子的CLDH具有良好的紫外阻隔性能.实验所用试剂均为分析纯.CLDH由NaOH,Na2CO3,MgSO4·7H2O,ZnSO4·7H2O,Al2(SO4)3·18H2O为原料,按文献[2]方法制备.ZnO+Al2O3复配物是按一定比例机械混合后,研磨,并在与CLDH相同的条件下煅烧…

关 键 词:双金属复合氧化物的结构与紫外阻隔性能  
收稿时间:2009-06-29
修稿时间:2009-06-29

Structure and Ultraviolet Absorbing and Screening Properties of Calcined Layered Double Hydroxides
Xu Guozhi.Structure and Ultraviolet Absorbing and Screening Properties of Calcined Layered Double Hydroxides[J].Chinese Journal of Applied Chemistry,1999,16(5):106-0.
Authors:Xu Guozhi
Institution:Xu Guozhi *
Abstract:The XRD patterns of different calcined layered double hydroxides(CLDH) and their ultraviolet absorbing and screening properties have been investigated. It has been found that a calcined layered double hydroxide(CLDH) containing zinc is very effective in absorbing and screening ultraviolet radiation. The crystal structure of a CLDH containing zinc is similar to that of ZnO and is not related to the crystal structure of Al 2O 3. It is not a simple combination of zinc oxide and aluminium oxide but a calcined layered double hydroxide in which part of the Zn 2 cations is replaced by Al 3 cations.
Keywords:calcined layered double hydroxide  structure  ultraviolet absorboscreening property
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