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| 反式环己烷羧酸衍生物的合成 | |
| 引用本文： | 唐洪,徐寿颐.反式环己烷羧酸衍生物的合成[J].应用化学,1999,16(2):85-83. |
| 作者姓名： | 唐洪 徐寿颐 |
| 作者单位： | 清华大学化学系 |
| 摘 要： | 低档液晶显示中所用的液晶材料，如联苯氰类、酯类等，具有高的粘度，低的清亮点及低的光化学、化学稳定性等缺点．随着液晶显示技术的发展，对高档液晶材料的要求越来越迫切．为了降低液晶材料的粘度指数，改造液晶分子的方法之一是用环己烷环代替分子中的苯环［１］．因... |
| 关 键 词： | 反式环己烷羧酸衍生物，顺反式异构体转换，选择性还原，液晶材料，合成 |
Synthesis of Transcyclohexane Carboxylic Acid Derivatives |
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| Tang Hong,Xu Shouyi.Synthesis of Transcyclohexane Carboxylic Acid Derivatives[J].Chinese Journal of Applied Chemistry,1999,16(2):85-83. | |
| Authors: | Tang Hong Xu Shouyi |
| Institution: | Tang Hong*,Xu Shouyi |
| Abstract: | Selective reduction of the phenyl ring beared carboxyl group was realized successfully with sodium and amyl alcohol at 140145 . Through cistrans isomerization trans4(4pentylphenyl)cyclohexyl carboxylic acid and trans4 cyclohexyl carboxylic acid were obtained in good yield and their structures were characterized by elemental analysis, IR, 13C NMR and MS measurements. |
| Keywords: | trans cyclohexane carboxylic acid derivative cistrans isomerization selective reduction liquid crystal material synthesis |
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