(CF(3))(4)Au(2)(C(5)H(5)N)(2)] - a new alkyl gold(ii) derivative with a very short Au-Au bond |
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| Authors: | David Zopes Corinna Hegemann Wieland Tyrra Sanjay Mathur |
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| Affiliation: | Institute of Inorganic Chemistry, University of Cologne, Greinstr. 6, D-50939 Cologne, Germany. Sanjay.Mathur@uni-koeln.de. |
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| Abstract: | A new gold(ii) species [(CF(3))(4)Au(2)(C(5)H(5)N)(2)] with a very short unsupported Au-Au bond (250.62(9) pm) was generated by photo irradiation of a silver aurate, [Ag(Py)(2)][Au(CF(3))(2)], unambiguously characterized by (19)F and (109)Ag NMR studies. |
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