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Mass transport controlled oxygen reduction at anthraquinone modified 3D-CNT electrodes with immobilized Trametes hirsuta laccase
Authors:Maciej Sosna  Leonard Stoica  Emma Wright  Jeremy D Kilburn  Wolfgang Schuhmann  Philip N Bartlett
Affiliation:Chemistry, University of Southampton, Southampton, SO17 1BJ, UK. pnb@soton.ac.uk.
Abstract:Carbon nanotubes covalently modified with anthraquinone were used as an electrode for the immobilization of Trametes hirsuta laccase. The adsorbed laccase is capable of oxygen reduction at a mass transport controlled rate (up to 3.5 mA cm(-2)) in the absence of a soluble mediator. The storage and operational stability of the electrode are excellent.
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