Molten state and solvent-free systems studied by NMR spectroscopy: addition reactions catalyzed by transition metal complexes |
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| Authors: | V. P. Ananikov I. P. Beletskaya |
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| Affiliation: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation;(2) Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992 Moscow, Russian Federation |
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| Abstract: | In the present review we address scarcely studied application area of NMR spectroscopy — investigation of molten state and solvent-free systems. In such a case NMR spectra are recorded without a solvent and without magnetic field stabilization on any nucleus. Taking our recent studies of catalytic addition of sulfur- and selenium-containing compounds to alkynes as examples, we describe most important practical aspects of NMR studies and their application for solving important chemical problems. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 740–746, April, 2008. |
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| Keywords: | NMR spectroscopy solvent-free reactions molten state reactions transition metal catalysis alkynes |
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